• 文献标题:   Advantages of nitrogen-doped graphene quantum dots as a green sensitizer with ZnO nanorod based photoanodes for solar energy conversion
  • 文献类型:   Article
  • 作  者:   MAJUMDER T, MONDAL SP
  • 作者关键词:   graphene quantum dots gqds, nitrogendoped graphene quantum dots ngqds, photoelectrochemical cell, zno nanorod, photoconversion efficiency, photoresponse
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Natl Inst Technol
  • 被引频次:   39
  • DOI:   10.1016/j.jelechem.2016.03.018
  • 出版年:   2016

▎ 摘  要

Graphene quantum dots (GQDs) and nitrogen -doped graphene quantum dots (N-GQDs) have been synthesized by a hydrothermal process. Optical absorption study revealed strong ultraviolet photoabsorption for both GQDs. An additional broad absorption band in the visible region has been observed for N doped GQDs. GQDs and N-GQDs both are highly luminescent and exhibit excitation dependent emission behaviors. Photoelectrochemical properties of GQD and N-GQD sensitized ZnO nanorods have been investigated in details. GQD modified nanorod photoanodes demonstrated superior photoconversion efficiency and incident photon to current conversion efficiency (IPCE) than pristine ZnO nanorods. N-GQD sensitized nanorods exhibited better photoelectrochemical properties than pristine GQD due to higher visible photoabsorption and lower interfacial resistance. (C) 2016 Elsevier B.V. All rights reserved.