• 文献标题:   Defected graphene as effective co-catalyst of CdS for enhanced photocatalytic activities
  • 文献类型:   Article
  • 作  者:   CHEN Y, WANG Y, ZHOU XH, ZHAO Y, PENG WC
  • 作者关键词:   photocatalysi, cocatalyst, defected graphene, hydrogen evolution, nitroaromatic reduction
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   0
  • DOI:   10.1007/s11356-020-09066-8 EA MAY 2020
  • 出版年:   2020

▎ 摘  要

Synthesis of highly efficient photocatalysts for energy and environment catalysis is still a big challenge in the materials field. Cadmium sulfide (CdS) is a promising visible light-driven photocatalyst, which can be composited with co-catalysts to increase its photo-activity and stability. In this study, a kind of graphene material with abundant structure defects (D-rGO) is synthesized by a two-step annealing process with nitrogen-doped rGO (N-rGO) as an intermediate. The high-temperature annealing could remove the doped heteroatoms to form structure defects with five or seven carbon atoms. The D-rGO is then used as co-catalyst for the modification of CdS nanoparticles, and enhanced photocatalytic activities could be obtained. A large hydrogen evolution rate of 102.7 mu mol h(-1) g(-1) is achieved, which is also effective for 4-nitrophenol reduction with a rate constant of 0.168 min(-1). The novel CdS/D-rGO composite contains no noble metals and could be used as multi-functional photocatalysts, thus should has great potential in the photocatalysis field.