• 文献标题:   BN-Graphene Composites Generated by Covalent Cross-Linking with Organic Linkers
  • 文献类型:   Article
  • 作  者:   KUMAR R, GOPALAKRISHNAN K, AHMAD I, RAO CNR
  • 作者关键词:  
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Jawaharlal Nehru Ctr Adv Sci Res
  • 被引频次:   32
  • DOI:   10.1002/adfm.201502166
  • 出版年:   2015

▎ 摘  要

Composites of boron nitride (BN) and carboxylated graphene are prepared for the first time using covalent cross-linking employing the carbodiimide reaction. The BN(1-x)G(x) (x approximate to 0.25, 0.5, and 0.75) obtained are characterized using a variety of spectroscopic techniques and thermogravimetric analysis. The composites show composition-dependent electrical resistivity, the resistivity decreasing with increase in graphene content. The composites exhibit microporosity and the x approximate to 0.75 composite especially exhibits satisfactory performance with high stability as an electrode in supercapacitors. The x approximate to 0.75 composite is also found to be a good electrocatalyst for the oxygen reduction reaction in fuel cells.