▎ 摘　　要

The enhancement of the reaction kinetics and structural stability of transition metal selenides during the discharge-charge process remains a big challenge in realizing the further application of sodium-ion batteries (SIBs). Herein, we report a novel anode by strategically constructing the heterointerfaces in hollow Co0.85Se-Fe7Se8 nanocuboids uniformly dispersed on reduced graphene oxide (Co0.85Se-Fe7Se8@rGO). The graphene decorated advanced hollow nanostructures could effectively buffer the volumetric stress and improve electrical conductivity. More importantly, by intelligently constructing heterostructures, a built-in electric field boosted on the heterointerface affords rapid ionic diffusion kinetics and improves electron transfer. With these merits, the Co0.85Se-Fe7Se8@rGO anode exhibits a distinguished reversible capacity of 332.3 mAh g(-1) at 0.1 A g(-1) after 200 cycles, even retaining 300.8 mAh g(-1) at 1.0 A g(-1) after 1000 cycles. This work casts a new light on the smart design of metal selenide anode materials for SIBs.