• 文献标题:   Nitrogen-Doped Porous Graphene-Based Aerogels toward Efficient Heavy Metal Ion Adsorption and Supercapacitor Applications
  • 文献类型:   Article
  • 作  者:   XIE ZK, ZHU JY, BI YT, REN HB, CHEN XC, YU HY
  • 作者关键词:   adsorption, chitosan, electrochemical performance, graphenebased aerogel
  • 出版物名称:   PHYSICA STATUS SOLIDIRAPID RESEARCH LETTERS
  • ISSN:   1862-6254 EI 1862-6270
  • 通讯作者地址:   Southwest Univ Sci Technol
  • 被引频次:   4
  • DOI:   10.1002/pssr.201900534
  • 出版年:   2020

▎ 摘  要

Graphene-based aerogels with different chitosan contents are selectively prepared by the hydrothermal reaction. It is found that with increasing chitosan content, the density of graphene-based aerogels decreases and their specific surface area enhances gradually. With the optimized mass ratio of chitosan to graphene oxide (4:1), its density and specific surface area are 11.0 mg cm(-3) and 616 m(2) g(-1), respectively. Due to the well-dispersed functional groups grafted on graphene and strong coordination ability to heavy metal ions, its saturated adsorption capacities for Cu2+ and Pb2+ are as high as 342.4 and 945.1 mg g(-1), respectively. After carbonization at 900 degrees C, the nitrogen element is incorporated into the skeleton of aerogels, and the resulting nitrogen-doped graphene-based aerogels show excellent electrochemical performance in supercapacitor applications. The present method paves the way for the synthesis of heteroatom-doped graphene-based aerogels for multifunctional special applications.