• 文献标题:   Multiscale Graphene-Based Materials for Applications in Sodium Ion Batteries
  • 文献类型:   Review
  • 作  者:   ZHANG Y, XIA XH, LIU B, DENG SJ, XIE D, LIU Q, WANG YD, WU JB, WANG XL, TU JP
  • 作者关键词:   anode, cathode, electrochemical energy storage, graphene, sodium ion batterie
  • 出版物名称:   ADVANCED ENERGY MATERIALS
  • ISSN:   1614-6832 EI 1614-6840
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   69
  • DOI:   10.1002/aenm.201803342
  • 出版年:   2019

▎ 摘  要

Scrupulous design and smart hybridization of bespoke electrode materials are of great importance for the advancement of sodium ion batteries (SIBs). Graphene-based nanocomposites are regarded as one of the most promising electrode materials for SIBs due to the outstanding physicochemical properties of graphene and positive synergetic effects between graphene and the introduced active phase. In this review, the recent progress in graphene-based electrode materials for SIBs with an emphasis on the electrode design principle, different preparation methods, and mechanism, characterization, synergistic effects, and their detailed electrochemical performance is summarized. General design rules for fabrication of advanced SIB materials are also proposed. Additionally, the merits and drawbacks of different fabrication methods for graphene-based materials are briefly discussed and summarized. Furthermore, multiscale forms of graphene are evaluated to optimize electrochemical performance of SIBs, ranging from 0D graphene quantum dots, 2D vertical graphene and reduced graphene oxide sheets, to 3D graphene aerogel and graphene foam networks. To conclude, the challenges and future perspectives on the development of graphene-based materials for SIBs are also presented.