• 文献标题:   Ni-Co layered double hydroxide on carbon nanorods and graphene nanoribbons derived from MOFs for supercapacitors
  • 文献类型:   Article
  • 作  者:   JIN HX, YUAN DQ, ZHU SY, ZHU XH, ZHU JL
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   17
  • DOI:   10.1039/c8dt01882k
  • 出版年:   2018

▎ 摘  要

In this study, carbon nanorods (CNR) and graphene nanoribbons (GNR) derived from metal-organic frameworks (MOFs) were first prepared by solvothermal method. Then, Ni-Co layered double hydroxide (LDH)/CNR and LDH/GNR composite materials for supercapacitors were synthesized using a facile co-precipitation method. With the help of GNR, the Ni-Co LDH/GNR composite material showed great specific capacity (1765 F g(-1)), rate performance (68% capacity retention when current density increased from 1 to 20 A g(-1)) and cycling stability (83% capacity retention after 2000 charge-discharge cycles at 5 A g(-1)). Furthermore, an asymmetric supercapacitor (ASC) with Ni-Co LDH/GNR as positive and activated carbon (AC) as negative electrodes was fabricated. The ASC device delivered a high energy density of 25.4 W h kg(-1) at power density of 749 W kg(-1) and exhibited excellent cycling stability (96% specific capacity retention after 5000 cycles).