• 文献标题:   Durability improving and corrosion-resistance mechanism of graphene oxide modified ultra-thin carbon paper used in PEM fuel cell
  • 文献类型:   Article
  • 作  者:   YANG PP, WU XB, XIE ZY, WANG P, LIU CB, HUANG QZ
  • 作者关键词:   corrosionresistance mechanism, graphene oxide, carbon paper, proton exchange membrane fuel cell, polytetrafluoroethylene
  • 出版物名称:   CORROSION SCIENCE
  • ISSN:   0010-938X EI 1879-0496
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   8
  • DOI:   10.1016/j.corsci.2017.10.025
  • 出版年:   2018

▎ 摘  要

The corrosion-resistance properties of modified ultra-thin carbon paper (CP) different graphene oxide (GO) content used in proton exchange membrane fuel cells (PEMFC) are studied for the first time. Results show that CP with 1 wt% GO has distinguished corrosion-resistance property (corrosion current: 5.539E-8A.cm(-2), minimum weight loss and contact angle variation). And mechanism analysis was found that the CP-1GO-P had uniform florine coating on some area of carbon fiber while T-CP-P has little. Moreover, the addition of GO could introduce more C=0 and C-O groups which interact with the florine atom, thus can strengthen the bonding of PTFE and matrix carbon effectively.