• 文献标题:   Preparation and properties of polyimide/graphene oxide nanocomposite films with Mg ion crosslinker
  • 文献类型:   Article
  • 作  者:   KONG JY, CHOI MC, KIM GY, PARK JJ, SELVARAJ M, HAN M, HA CS
  • 作者关键词:   polyimide, graphene oxide, crosslinking, magnesium ion, propertie
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   52
  • DOI:   10.1016/j.eurpolymj.2012.05.015
  • 出版年:   2012

▎ 摘  要

Polyimide(PI)/graphene oxide(GO) nanocomposite films were prepared by chemical crosslinking using small amounts of divalent Mg ions. The PI/GO nanocomposites showed enhanced tensile properties compared to pristine PI due to the presence of exfoliated GO in the PI matrix as well as crosslinking between poly(amic acid) (PAA), which is a precursor of PI, and GO by Mg ions. The hydrogen bonds between PM and GO suppressed the phase separation between PI and GO, and small amounts of Mg ions can bond between the oxygen functional groups and carboxylate groups of GO and PM. (C) 2012 Elsevier Ltd. All rights reserved.