• 文献标题:   Water-Mediated Spontaneously Dynamic Oxygen Migration on Graphene Oxide with Structural Adaptivity for Biomolecule Adsorption*
  • 文献类型:   Article
  • 作  者:   TU YS, ZHAO L, SUN JJ, WU YY, ZHOU XJ, CHEN L, LEI XL, FANG HP, SHI GS
  • 作者关键词:   68, 37, d, 68, 90, +g, 61, 48, gh, 87, 90, +y
  • 出版物名称:   CHINESE PHYSICS LETTERS
  • ISSN:   0256-307X EI 1741-3540
  • 通讯作者地址:   Yangzhou Univ
  • 被引频次:   0
  • DOI:   10.1088/0256-307X/37/6/066803
  • 出版年:   2020

▎ 摘  要

We theoretically and experimentally show that, with water being adsorbed, the graphene oxide (GO) is converted to a spontaneously dynamic covalent material under ambient conditions, where the dominated epoxy and hydroxyl groups are mediated by water molecules to spontaneously break/reform their C-O bonds to achieve dynamic oxygen migration. This dynamic material presents structural adaptivity for response to biomolecule adsorption. Both density functional theory calculations and ab initio molecular dynamics simulations demonstrate that this spontaneously dynamic characteristics is attributed to the adsorption of water molecules, which sharply reduces the barriers of these oxygen migration reactions on GO to the level less than or comparable to the hydrogen bonding energy in liquid water.