• 文献标题:   One-Step Preparation of Graphene-Supported Anatase TiO2 with Exposed {001} Facets and Mechanism of Enhanced Photocatalytic Properties
  • 文献类型:   Article
  • 作  者:   GU LA, WANG JY, CHENG H, ZHAO YZ, LIU LF, HAN XJ
  • 作者关键词:   rgo/tio2 hybrid nanocomposite, tio2 {001} facet, photocatalytic mechanism
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   170
  • DOI:   10.1021/am303274t
  • 出版年:   2013

▎ 摘  要

Anatase TiO2 nanosheets supported on reduced graphene oxide (RGO) were synthesized via a one-step, solvothermal method. During the solvothermal step, graphene oxide (GO) was reduced to RGO, and, subsequently, anatase TiO2 with 73.7% exposed {001} facets was grown in situ on the surfaces of the RGO nanosheets. Compared with pure TiO2, the RGO/TiO2 hybrid nanocomposite had improved photoactivity as a result of effective photoinduced electron transfer from TiO2 to the RGO acceptor through interfacial interactions. Trapping tests showed that the oxidation of dye molecules proceeded for about 22% through the reaction with OH radicals, and the remaining 78% occurred via direct interactions with holes. The holes left in TiO2 crystals were the main reason for the enhanced photocatalytic properties of the RGO/TiO2 composite. This paper not only reports the fabrication of highly active photocatalysts but also gives deeper insight into the photocatalytic mechanism of carbon/TiO2 composites.