• 文献标题:   Reduced graphene oxide/TiO2(B) nanocomposite-modified separator as an efficient inhibitor of polysulfide shuttling in Li-S batteries
  • 文献类型:   Article
  • 作  者:   CHEN P, WANG ZX, ZHANG BY, LIU H, LIU WD, ZHAO JX, MA ZH, DONG WY, SU ZM
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:   Changchun Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1039/c9ra10185c
  • 出版年:   2020

▎ 摘  要

The shutting effect in lithium-sulfur (Li-S) batteries hinders their widespread application, which can be restrained effectively by a modified separator. In this work, a composite of reduced graphene oxide and beta-phase TiO2 nanoparticles (RGO/TiO2(B)) is designed as a separator modification material for improving the electrochemical behavior of Li-S batteries. The TiO2(B) nanoparticles are in situ prepared and tightly adhere to the RGO layer. A series of examinations demonstrated that the RGO/TiO2(B)-coated separator efficiently inhibits the polysulfide shuttling phenomenon by the cooperative effect of physical adsorption and chemical binding. Specifically, as modified separators, a comparison between TiO2(B) and anatase TiO2(A) each composited with RGO has been conducted. The TiO2(B) sample not only exhibits a superior blocking character of migrating polysulfides, but also enhances battery electrochemical kinetics by fast Li ion diffusion.