• 文献标题:   Synthesis and characterization of graphene nanocomposites for non-linear optical applications
  • 文献类型:   Article
  • 作  者:   RAI R, KREIN D, SLAGLE J, COOPER T, MURATORE C
  • 作者关键词:   graphene, nonlinear optic, nanocomposite
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:   Univ Dayton
  • 被引频次:   0
  • DOI:   10.1016/j.diamond.2018.09.009
  • 出版年:   2018

▎ 摘  要

Graphene shows remarkable non-linear optical behavior. Above a particular incident light intensity threshold, transmission is attenuated. Unfortunately, capitalizing on the unique properties of graphene can be a challenge because the material itself is hard to handle, unless it is integrated with other materials. The purpose of this work is to develop graphene-based nano-composites for non-linear optical applications. Few and single layer graphene flakes were synthesized through liquid phase exfoliation of graphite in 1-Methyl-2-pyrrolidinon (NMP), and characterized via Raman and transmission electron microscopy. Synthesis parameters for stable, high quality graphene suspensions were identified and graphene was integrated into nano-composites prepared via sol-gel methods. In addition to structural and chemical characterization, I-scan measurements revealed the composites demonstrated non-linear optical behavior with a cut-off frequency tunable with few layer graphene concentration in the composite.