• 文献标题:   Directed growth of graphene nanomesh in purified argon via chemical vapor deposition
  • 文献类型:   Article
  • 作  者:   SUN HB, FU C, SHEN X, YANG WC, GUO PF, LU Y, LUO YS, YU BH, WANG XG, WANG CL, XU JQ, LIU JF, SONG FQ, WANG GH, WAN JG
  • 作者关键词:   graphene nanomesh, oxidizing reaction, purified ar, preheating
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Xinyang Normal Univ
  • 被引频次:   0
  • DOI:   10.1088/1361-6528/aa7044
  • 出版年:   2017

▎ 摘  要

Graphene nanomeshes (GNMs), new graphene nanostructures with tunable bandgaps, are potential building blocks for future electronic or photonic devices, and energy storage and conversion materials. In previous works, GNMs have been successfully prepared on Cu foils by the H-2 etching effect. In this paper, we investigated the effect of Ar on the preparation of GNMs, and how the mean density and shape of them vary with growth time. In addition, scanning electron microscopy (SEM) and high resolution transmission electron microscopy (TEM) revealed the typical hexagonal structure of GNM. Atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS) indicated that large copper oxide nanoparticles produced by oxidization in purified Ar can play an essential catalytic role in preparing GNMs. Then, we exhibited the key reaction details for each growth process and proposed a growth mechanism of GNMs in purified Ar.