• 文献标题:   Monochlorotriazinyl-beta-cyclodextrin Grafted on Graphene Oxide as an Attractive Green Heterogeneous Nanoreactor for Selective Oxidation Reaction with NBS in Water
  • 文献类型:   Article
  • 作  者:   POUR SR, DINARI M, ABDOLMALEKI A
  • 作者关键词:   graphene oxide go, green nanoreactor, monochlorotriazinylbetacyclodextrin, organocatalysi, oxidation
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Isfahan Univ Technol
  • 被引频次:   0
  • DOI:   10.1002/slct.201900962
  • 出版年:   2019

▎ 摘  要

Graphene oxide supported monochlorotriazinyl-beta-cyclodextrin (GO-MCT- beta-CD) as a green nanoreactor was synthesized via a simple chemical bonding method and analyzed by XRD, FT-IR, CHNS, FESEM and Raman spectroscopy. The prepared GO-MCT-beta-CD worked as a nanoreactor for the green oxidation reactions of benzyl alcohol derivatives with N-bromo succinimide to their corresponding aldehydes under green conditions. Depending on the different substituents of various benzyl alcohols, good to excellent yields were obtained and no over-oxidation was observed. It can be considered an attractive methodology due to the use of water in the presence of "solid metal-free nanoreactor" as a green reaction system at the room temperature. Easy separation and excellent reusability of the catalyst were other advantages of this methodology.