• 文献标题:   In situ growth of porphyrinic metal-organic framework nanocrystals on graphene nanoribbons for the electrocatalytic oxidation of nitrite
  • 文献类型:   Article
  • 作  者:   KUNG CW, LI YS, LEE MH, WANG SY, CHIANG WH, HO KC
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   36
  • DOI:   10.1039/c6ta02563c
  • 出版年:   2016

▎ 摘  要

Graphene nanoribbons (GNRs) are incorporated with the nanocrystals of a porphyrinic metal-organic framework, MOF-525, by solvothermally growing MOF-525 in a suspension of well-dispersed GNRs. A nanocomposite, which is composed of the MOF-525 nanocrystals interconnected by numerous one-dimensional GNRs, is successfully synthesized. Due to the excellent dispersity, uniform thin films of the MOF-525/GNR nanocomposite can be simply deposited on conducting glass substrates by using drop casting. The obtained thin film of the MOF-525/GNR nanocomposite is applied for electrochemical nitrite sensors. The MOF-525 nanocrystals serve as a high-surface-area electrocatalyst toward nitrite and the interconnected GNRs act as conductive bridges to provide facile charge transport. The thin film of the MOF-525/GNR nanocomposite thus exhibits a much better electrocatalytic activity for the oxidation of nitrite compared to the pristine MOF-525 thin film.