• 文献标题:   Solid-state microwave irradiation synthesis of high quality graphene nanosheets under hydrogen containing atmosphere
  • 文献类型:   Article
  • 作  者:   PARK SH, BAK SM, KIM KH, JEGAL JP, LEE SI, LEE J, KIM KB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   95
  • DOI:   10.1039/c0jm01007c
  • 出版年:   2011

▎ 摘  要

High quality graphene nanosheets were fabricated within 1 min by solid-state microwave irradiation of a mixture of graphite oxide and graphene nanosheets under a hydrogen atmosphere. The graphene nanosheets in the mixture acted as an effective microwave susceptor under microwave irradiation synthesis, and could provide sufficiently rapid heating for the effective exfoliation of graphite oxide. A hydrogen containing atmosphere played important roles in improving the quality of the graphene nanosheets by increasing the level of reduction and preventing the formation of defects in the graphene nanosheets. The graphene nanosheets thus obtained exhibited a specific surface area of 586 m(2) g(-1) and an outstanding carbon/oxygen ratio of 18.5.