• 文献标题:   Synthesis, characterization and electrical properties of silicon-doped graphene films
  • 文献类型:   Article
  • 作  者:   WANG ZG, LI PJ, CHEN YF, LIU JB, ZHANG WL, GUO Z, DONG MD, LI YR
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY C
  • ISSN:   2050-7526 EI 2050-7534
  • 通讯作者地址:   Univ Elect Sci Technol China
  • 被引频次:   36
  • DOI:   10.1039/c5tc00563a
  • 出版年:   2015

▎ 摘  要

Theoretical calculations have predicted that silicon doping modifies the electronic structure of graphene; however, it is difficult to synthesize high-quality silicon-doped graphene (SiG), thus the electrical properties of SiG have still remained unexplored. In this study, a monolayer SiG film was synthesized by chemical vapour deposition using triphenylsilane (C18H15Si) as a sole solid source, which provides both carbon and silicon atoms. The silicon doping content is similar to 2.63 at%, and silicon atoms are incorporated into the graphene lattice with pure Si-C bonds. Furthermore, electrical studies reveal that the as-synthesized SiG film shows a typical p-type doping behaviour with a considerably high carrier mobility of about 660 cm(2) V-1 s(-1) at room temperature. In addition, due to the single doping structure of Si-C bonds, the SiG film can be expected to be used as an excellent platform for studying silicon doping effects on the physical and chemical properties of graphene.