• 文献标题:   Synthesis and application of graphene-silver nanowires composite for ammonia gas sensing
  • 文献类型:   Article
  • 作  者:   TRAN QT, HUYNH TMH, TONG DT, TRAN VT, NGUYEN ND
  • 作者关键词:   graphene, hummers method, silver nanowire, polyol method, ammonia gas sensing
  • 出版物名称:   ADVANCES IN NATURAL SCIENCESNANOSCIENCE NANOTECHNOLOGY
  • ISSN:   2043-6254 EI 2043-6262
  • 通讯作者地址:   Vietnam Natl Univ Ho Chi Minh City VNU HCM
  • 被引频次:   18
  • DOI:   10.1088/2043-6262/4/4/045012
  • 出版年:   2013

▎ 摘  要

Graphene, consisting of a single carbon layer in a two-dimensional (2D) lattice, has been a promising material for application to nanoelectrical devices in recent years. In this study we report the development of a useful ammonia (NH3) gas sensor based on graphene-silver nanowires 'composite' with planar electrode structure. The basic strategy involves three steps: (i) preparation of graphene oxide (GO) by modified Hummers method; (ii) synthesis of silver nanowires by polyol method; and (iii) preparation of graphene and silver nanowires on two electrodes using spin and spray-coating of precursor solutions, respectively. Exposure of this sensor to NH3 induces a reversible resistance change at room temperature that is as large as Delta R/R-0 similar to 28% and this sensitivity is eight times larger than the sensitivity of the 'intrinsic' graphene based NH3 gas sensor (Delta R/R-0 similar to 3, 5%). Their responses and the recovery times go down to similar to 200 and similar to 60 s, respectively. Because graphene synthesized by chemical methods has many defects and small sheets, it cannot be perfectly used for gas sensor or for nanoelectrical devices. The silver nanowires are applied to play the role of small bridges connecting many graphene islands together to improve electrical properties of graphene/silver nanowires composite and result in higher NH3 gas sensitivity.