• 文献标题:   Flexible foams of graphene entrapped SnO2-Co3O4 nanocubes with remarkably large and fast lithium storage
  • 文献类型:   Article
  • 作  者:   GUO JX, ZHU HF, SUN YF, TANG L, ZHANG X
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   20
  • DOI:   10.1039/c6ta06626g
  • 出版年:   2016

▎ 摘  要

In developing flexible lithium-ion batteries (LIBs), fabrication of a high-performance electrode with good flexibility and stability is desirable, yet remains challenging. Herein, a flexible integrated electrode is introduced based on layer-by-layer packed graphene sheets entrapped SnO2-Co3O4 nanocubes. The rationally selected composition, polyhedral nanostructures, and proper construction of the specific architecture successfully trigger a synergistic lithium storage effect, assuring the partial reversible conversion of SnO2 and interfacial lithium storage of graphene, which are responsible for the remarkably high reversible capacity of 1665 mA h g(-1) after 100 cycles at 100 mA g(-1). Large and stable cyclic performance as well as long cyclic life is also obtained at a high current density of 1 A g(-1) (1208 mA h g(-1) after 1000 cycles). More importantly, the free-standing electrode can well retain its flexible feature even after 300 repeated electrochemical cycles, making it a promising candidate for a high-performance and stable electrode for flexible LIBs.