▎ 摘　　要

Graphene-based assemblies are gaining attention as a viable alternate to boost the efficiency of various catalytic and storage reactions in energy conversion applications. The use of reduced graphene oxide has already proved useful in collecting and transporting charge in photoelectrochemical solar cells photocatalysis, and electrocatalysis. In many of these applications, the flat carbon serves as a scaffold to anchor metal and semiconductor nanoparticles and assists in promoting selectivity and efficiency of the catalytic process. Covalent and noncovalent interaction with organic molecules is another area that is expected to provide new frontiers in graphene research. Recent advances in manipulating graphene-based two-dimensional carbon architecture for energy conversion are described.