• 文献标题:   Electrochemical intercalation of tetraethylammonium tetrafluoroborate into KOH-treated carbon consisting of multi-graphene sheets for an electric double layer capacitor
  • 文献类型:   Article
  • 作  者:   TAKEUCHI M, KOIKE K, MARUYAMA T, MOGAMI A, OKAMURA M
  • 作者关键词:   graphitelike layer, kohtreated carbon, electrochemical intercalation, edlc
  • 出版物名称:   DENKI KAGAKU
  • ISSN:   0366-9297
  • 通讯作者地址:   Jeol Ltd
  • 被引频次:   41
  • DOI:   10.5796/kogyobutsurikagaku.66.1311
  • 出版年:   1998

▎ 摘  要

Carbons produced by calcination at 700 similar to 850 degrees C, of the materials derived from petroleum cokes and pitches consist of well-grown graphite-like layers with an average inter-layer distance of d(infinity 2) = 0.35 similar to 0.365 nm. Additional heat treatment of the carbon with KOH at 800 degrees C can provide the expansion of inter-layer distance up to d(infinity 2) = 0.36 similar to 0.385 nm and the latent ability of electrochemical intercalation of Et4N+ and BF4- in PC into the multi-graphene layers. Using the KOH-treated carbons as electrodes of EDLC, a high-density energy store such as 25 similar to 30 F/cm(3) of dry total electrodes operating at 3.5 similar to 4.0 V is available when the depth of the cell is rigidly restricted.