• 文献标题:   In situ polymerization of graphene nanosheets and polyurethane with enhanced mechanical and thermal properties
  • 文献类型:   Article
  • 作  者:   WANG X, HU YA, SONG L, YANG HY, XING WY, LU HD
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   259
  • DOI:   10.1039/c0jm03710a
  • 出版年:   2011

▎ 摘  要

Polyurethane (PU) composites reinforced with graphene nanosheets (GNSs) were prepared by in situ polymerization. Graphene nanosheets, which were derived from chemically reduced graphite oxide (GO) nanosheets, were characterized by solid-state C-13 MAS NMR, XRD and FTIR. A morphological study showed that, due to the formation of chemical bonds, the GNS was dispersed well in the PU matrix. With the incorporation of 2.0 wt% of GNSs, the tensile strength and storage modulus of the PU increased by 239% and 202%, respectively. The nanocomposites displayed high electrical conductivity, and good thermal stability of PU was also achieved. The facile and rapid technique presented here will provide an effective and promising method of preparing graphene-based polymer composites.