• 文献标题:   Probing the effects of 2D confinement on hydrogen dynamics in water and ice adsorbed in graphene oxide sponges
  • 文献类型:   Article
  • 作  者:   ROMANELLI G, SENESI R, ZHANG X, LOH KP, ANDREANI C
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Univ Roma Tor Vergata
  • 被引频次:   11
  • DOI:   10.1039/c5cp05240h
  • 出版年:   2015

▎ 摘  要

We studied the single particle dynamics of water and ice adsorbed in graphene oxide (GO) sponges at T = 293 K and T = 20 K. We used Deep Inelastic Neutron Scattering (DINS) at the ISIS neutron and muon spallation source to derive the hydrogen mean kinetic energy, < E-K >, and momentum distribution, n(p). The goal of this work was to study the hydrogen dynamics under 2D confinement and the potential energy surface, fingerprinting the hydrogen interaction with the layered structure of the GO sponge. The observed scattering is interpreted within the framework of the impulse approximation. Samples of both water and ice adsorbed in GO show n(p) functions with almost harmonic and anisotropic line shapes and < E-K > values in excess of the values found at the corresponding temperatures in the bulk. The hydrogen dynamics are discussed in the context of the interaction between the interfacial water and ice and the confining hydrophilic surface of the GO sponge.