• 文献标题:   Rheological Behavior - Electrical and Thermal Properties of Polypyrrole/Graphene Oxide Nanocomposites
  • 文献类型:   Article
  • 作  者:   MANIVEL P, KANAGARAJ S, BALAMURUGAN A, PONPANDIAN N, MANGALARAJ D, VISWANATHAN C
  • 作者关键词:   composite, conducting polymer, rheology, thermal propertie
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Bharathiar Univ
  • 被引频次:   14
  • DOI:   10.1002/app.40642
  • 出版年:   2014

▎ 摘  要

Polypyrrole/graphene oxide (Ppy/GO) nanocomposites were synthesized via in situ polymerization of pyrrole in the presence of GO at various proportions (1-5%). They were characterized to determine their electrical, thermal, and rheological properties by various techniques. The aim of this study was to determine the rheological behavior of Ppy/GO nanocomposite at different mass ratios (100 : 1, 100 : 2, 100 : 3, 100 : 4, and 100 : 5%) and temperature (25-180 degrees C) using a rotational mode in cone-plate method. The shear stress ( Pa) and viscosity ( Pa s) values of the nanocomposites increased with the increase in GO mass ratio added to Ppy, which was accompanied by an increased flexibility of the nanocomposites due to the higher aspect ratio of the GO sheet. Hence, it is suggested that the GO sheets are effective for the reinforcement of Ppy thereby significantly improvising its thermal stability, electrical conductivity, and rheological properties. (c) 2014 Wiley Periodicals, Inc.