• 文献标题:   Efficient dye-sensitized solar cells with CoSe/graphene composite counter electrodes
  • 文献类型:   Article
  • 作  者:   CHEN XB, YANG QM, MENG Q, ZHANG ZF, ZHANG JY, LIU LM, ZHANG XW, YANG PZ
  • 作者关键词:   alloy electrocatalyst, graphene, counter electrode, dyesensitized solar cell
  • 出版物名称:   SOLAR ENERGY
  • ISSN:   0038-092X
  • 通讯作者地址:   Yunnan Normal Univ
  • 被引频次:   13
  • DOI:   10.1016/j.solener.2017.01.035
  • 出版年:   2017

▎ 摘  要

CoSe/graphene nanocomposites with various graphene content were synthesized via a simple low temperature hydrothermal method and used as counter electrode (CE) in dye sensitized solar cells (DSSC). SEM shows that CoSe0.85 particle sare self-assembled to a potato-chip-like morphology and loaded on graphene sheets. Cyclic voltammetry and electrochemical impedance spectroscopy and Tafel polarization analyses revealed that the CoSe0.85/graphene composite CE with the weight ratio of graphene of 75% exhibited higher electrocatalytic activity for the reduction of triiodide to iodide and lower charge transfer resistance at the CE/electrolyte interface than the other compositions. The DSSC with the optimized CoSe0.85/graphene as composite CE produces a maximum power conversion efficiency of 8.17%, which is better than bare CoSe0.85 CE. (C) 2017 Elsevier Ltd. All rights reserved.