• 文献标题:   Nitrogen-Doped Holey Graphene Film-Based Ultrafast Electrochemical Capacitors
  • 文献类型:   Article
  • 作  者:   ZHOU QQ, ZHANG M, CHEN J, HONG JD, SHI GQ
  • 作者关键词:   nitrogen doping, holey graphene, meso/macropore, ultrafast electrochemical capacitor, ac linefiltering
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   34
  • DOI:   10.1021/acsami.6b05601
  • 出版年:   2016

▎ 摘  要

The comitiercialiied aluminum electrolytic.capacitors (AECs) currently used for alternating current (AC) line filtering are usually the largest components in the electronic circuits because of their low specific capacitances and bulky sizes. Herein, nitrogen-doped holey graphene (NHG) films were prepared by thermal annealing the composite films of polyvinylpyrrolidone (PVP), graphene oxide (GO), and ferric oxide (Fe2O3) nanorods followed by chemical etching with hydrochloride acid. The typical electrochemical capacitor with NHG electrodes exhibited high areal and volumetric specific capacitances of 478 mu F cm(-2) and 1.2 F cm(-3) at 120 Hz, ultrafast frequency response with a phase angle of -81.2 degrees and a resistor-capacitor time constant of 203 mu S at 120 Hz, as well as excellent cycling stability. Thus, it is promising to replace conventional AEC for AC line-filtering in miniaturized electronics.