▎ 摘　　要

A novel, facile and scalable process of simultaneous activation and templating is developed for in situ synthesis of graphene-enhanced 3D hierarchical porous carbon nanobelt networks uniformly anchored with polycrystalline Fe3O4 nanoparticles (5-45 nm) (Fe3O4-rGO/poly(vinyl alcohol) (PVA)-derived carbon) as a high-performance supercapacitor electrode. During the synthesis, 3D self-assembled NaCl particles are adopted as a structural template to direct the growth of 3D carbon nanobelt networks with interconnected macropores, KOH is used as an activating reagent to generate porous nanobelts with masses of micro-, meso-and macropores, and graphene sheets behave as a chemical activator to promote the growth of hierarchical porous thin nanobelts. The resulting Fe3O4-rGO/PVA-derived carbon electrode leads to a combination of the redox pseudo-capacitance of Fe3O4 and the electric double-layer capacitance of the carbon species with a remarkably high capacitivity (538.8 F g(-1) at 5 A g(-1)) and outstanding cycle performance (similar to 590 F g(-1) after 5000 cycles at 5 A g(-1)). This work offers a new strategy for preparation of 3D hierarchical porous carbon networks for future applications. (C) 2017 Published by Elsevier Ltd.