• 文献标题:   A Three-Dimensionally Structured Electrocatalyst: Cobalt-Embedded Nitrogen-Doped Carbon Nanotubes/Nitrogen-Doped Reduced Graphene Oxide Hybrid for Efficient Oxygen Reduction
  • 文献类型:   Article
  • 作  者:   WEI CT, WANG HJ, EID K, KIM J, KIM JH, ALOTHMAN ZA, YAMAUCHI Y, WANG L
  • 作者关键词:   carbon nanotube, electrocatalysi, graphene, hybrid material, oxygen reduction reaction, porous material
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Zhejiang Univ Technol
  • 被引频次:   24
  • DOI:   10.1002/chem.201604113
  • 出版年:   2017

▎ 摘  要

To develop low-cost and efficient oxygen reduction reaction (ORR) catalysts, a novel hybrid comprising cobalt-embedded nitrogen-doped carbon nanotubes and nitrogen-doped reduced graphene oxide (Co-NCNT/NrGO-800) was simply prepared by pyrolysis. The combination of nanotubes and graphene, and the efficient doping with cobalt and nitrogen, greatly contribute to the excellent ORR performance. This optimized Co-NCNT/NrGO catalyst exhibits a positive onset potential of 0.91 V and a half-wave potential of 0.82 V, combined with a relatively low peroxide yield, better durability, and better methanol tolerance than commercially available Pt/C, which makes it a promising candidate as a low-cost and effective non-precious-metal ORR catalyst.