• 文献标题:   Graphene Paste Electrode: Analytical Applications for the Quantification of Dopamine, Phenolic Compounds and Ethanol
  • 文献类型:   Article
  • 作  者:   GUTIERREZ F, COMBA FN, GASNIER A, GUTIERREZ A, GALICIA L, PARRADO C, RUBIANES MD, RIVAS GA
  • 作者关键词:   graphene paste electrode, composite electrode, ascorbic acid, dopamine, nadh, enzymatic biosensor, phenol biosensor, ethanol biosensor, polyphenol oxidase, alcohol dehydrogenase
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Univ Nacl Cordoba
  • 被引频次:   14
  • DOI:   10.1002/elan.201400247
  • 出版年:   2014

▎ 摘  要

This work reports the analytical applications of a graphene paste electrode (GrPE) for the quantification of dopamine, ethanol and phenolic compounds. Dopamine was detected by differential pulse voltammetry-adsorptive stripping with medium exchange at submicromolar levels even in the presence of high excess of ascorbic acid and serotonin. The electrocatalytic activity of graphene towards the oxidation of NADH and the reduction of quinones allowed the sensitive amperometric determination of ethanol and phenols using GrPE modified with alcohol dehydrogenase/NAD(+) or polyphenol oxidase, respectively, with successful applications in real samples like alcoholic beverages and tea.