• 文献标题:   Reduced Graphene Oxide Inserted into PEDOT:PSS Layer to Enhance the Electrical Behaviour of Light-Emitting Diodes
  • 文献类型:   Article
  • 作  者:   RODRIGUEZMAS F, FERRER JC, ALONSO JL, DE AVILA SF, VALIENTE D
  • 作者关键词:   cadmium sulphide, pvk, hybrid lightemitting device, electroluminescence, nanocrystal, reduced graphene oxide
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.3390/nano11030645
  • 出版年:   2021

▎ 摘  要

In this study, poly(9-vinylcarbazole) (PVK)-based LEDs doped with reduced graphene oxide (rGO) and cadmium sulphide (CdS) nanocrystals were fabricated by spin-coating. The hybrid LED structure was a layer sequence of glass/indium tin oxide (ITO)/PEDOT:PSS|rGO/PVK/Al. rGO was included in the poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) layer due to its energy bands being close to PEDOT:PSS bands, and the possibility of using water for dispersing both polymer and flakes. Optical properties such as photoluminescence and UV-Vis absorption were not affected by the addition of rGO to the PEDOT:PSS solution. However, PVK-based LEDs with rGO showed increased current density compared to those without rGO in the hole transporting layer. Higher electroluminescence intensities were observed for rGO-enriched LEDs, although the shape of the spectrum was not modified. LEDs including CdS nanocrystals in the poly(9-vinylcarbazole) emissive layer did not show such dependence on the rGO presence. Though the addition of rGO to PEDOT:PSS still produces a slightly higher current density in CdS doped LEDs, this growth is no longer proportional to the rGO load.