• 文献标题:   One-pot synthesis of graphene supported platinum-cobalt nanoparticles as electrocatalysts for methanol oxidation
  • 文献类型:   Article
  • 作  者:   KEPENIENE V, TAMASAUSKAITETAMASIUNAITE L, JABLONSKIENE J, SEMASKO M, VAICIUNIENE J, VAITKUS R, NORKUS E
  • 作者关键词:   composite material, chemical synthesi, electrochemical propertie
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Ctr Phys Sci Technol
  • 被引频次:   6
  • DOI:   10.1016/j.matchemphys.2015.12.010
  • 出版年:   2016

▎ 摘  要

In the present study the graphene supported platinum cobalt nanoparticles were prepared via microwave synthesis. The composition of prepared catalysts was examined by Inductively Coupled Plasma Optical Emission Spectroscopy. The shape and size of catalyst particles were determined by Transmission Electron Microscopy. The electrocatalytic activity of the graphene supported platinum cobalt nano particles was investigated towards the electro-oxidation of methanol in an alkaline medium. It has been found that the graphene supported platinum cobalt nanoparticles having the Pt:Co molar ratio 1:7 show the highest activity towards the electro-oxidation of methanol among the catalysts with the Pt:Co molar ratios equal to 1:1 and 1:44, graphene supported bare Co and Pt/C catalysts. (C) 2015 Elsevier B.V. All rights reserved.