• 文献标题:   Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement
  • 文献类型:   Article
  • 作  者:   YANG HF, LI FH, SHAN CS, HAN DX, ZHANG QX, NIU L, IVASKA A
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   507
  • DOI:   10.1039/b901421g
  • 出版年:   2009

▎ 摘  要

Polydisperse, functionalized, chemically converted graphene (f-CCG) nanosheets, which can be homogeneously distributed into water, ethanol, DMF, DMSO and 3-aminopropyltriethoxysilane (APTS), were obtained via facile covalent functionalization with APTS. The resulting f-CCG nanosheets were characterized by FTIR, XPS, TGA, EDX, AFM, SEM, and TEM. Furthermore, the f-CCG nanosheets as reinforcing components were extended into silica monoliths. Compressive tests revealed that the compressive failure strength and the toughness of f-CCG-reinforced APTS monoliths at 0.1 wt% functionalized, chemically converted graphene sheets compared with the neat APTS monolith were greatly improved by 19.9% and 92%, respectively.