• 文献标题:   Graphene Oxide and Silver Ions Coassisted Zeolitic Imidazolate Framework for Antifouling and Uranium Enrichment from Seawater
  • 文献类型:   Article
  • 作  者:   GUO XJ, CHEN RR, LIU Q, LIU JY, ZHANG HS, YU J, LI RM, ZHANG ML, WANG J
  • 作者关键词:   graphene oxide, zeolitic imidazolate framework, silver ion, antifouling, uranium extraction from seawater
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   19
  • DOI:   10.1021/acssuschemeng.8b06391
  • 出版年:   2019

▎ 摘  要

Seawater environmental limitation from antifouling due to microorganisms presents a great challenge in uranium extraction from seawater. Herein, a bifunctional graphene oxide-silver ions-zeolitic imidazolate framework-67 composite was successfully synthesized for minimizing the effects of antifouling in the enrichment of uranium. A series of antialga assays were carried out using Phaeodactylum tricornutum as a fouling template alga. Interestingly, the adsorbents clearly display an algae inhibitory behavior with more than 80% alga death rate after 7 days, as well as enhance U(VI) adsorption performance via the coassistance of graphene oxide and silver ions. Adsorption amounts of composites reach 189.36 mg g(-1) at a pH 7.0. In addition, composites still retain a high U(VI) adsorption amount which increases by 177% in comparison to the zeolitic imidazolate framework-67 at pH 8.0 (nearly seawater pH). The adsorption experiment was carried out in actual seawater, with the removal rate of U(VI) reaching nearly 70%, which proves that the graphene oxide and silver ions coassisted zeolitic imidazolate framework-67 composites are applicable to a seawater environment.