• 文献标题:   Few-Layer Graphene as a Support Film for Transmission Electron Microscopy Imaging of Nanoparticles
  • 文献类型:   Article
  • 作  者:   MCBRIDE JR, LUPINI AR, SCHREUDER MA, SMITH NJ, PENNYCOOK SJ, ROSENTHAL SJ
  • 作者关键词:   graphene, fewlayer graphene, transmission electron microscopy, aberrationcorrected scanning transmission electron microscopy nanocrystal, nanoparticle, cadmium selenide, copper indium selenide
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Vanderbilt Univ
  • 被引频次:   18
  • DOI:   10.1021/am900608j
  • 出版年:   2009

▎ 摘  要

One consistent limitation for high-resolution imaging of small nanoparticles is the high background signal from the amorphous carbon support film. With interest growing for smaller and smaller nanostructures, state of the art electron microscopes are becoming necessary for rudimentary tasks, such as nanoparticle sizing. As a monolayer of carbon, free-standing graphene represents the ultimate support film for nanoparticle imaging. In this work, conventional high-resolution transmission electron microscopy (HRTEM) and aberration-corrected scanning transmission electron microscopy (STEM) were used cc assess the benefits and feasibility of few-layer graphene support films. Suspensions of few-layer graphene to produce the support films were prepared by simple sonication of exfoliated graphite. The greatest benefit was observed for conventional HRTEM, where lattice resolved imaging of sub 2 nm CdSe nanocrystals was achieved. The few-layer graphene films were also used as a support him For C-s-corrected STEM and electron energy loss spectroscopy of CuInSe2 nanocrystals.