• 文献标题:   Role of residual polymer on chemical vapor grown graphene by Raman spectroscopy
  • 文献类型:   Article
  • 作  者:   KOO E, JU SY
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   20
  • DOI:   10.1016/j.carbon.2015.01.055
  • 出版年:   2015

▎ 摘  要

Although various applications extensively utilize polymer-assisted graphene transfer step, the role of residual polymer on graphene was not well-understood. Here, we report the effect of poly (methyl methacrylate) (PMMA) on chemical vapor deposition-grown hexagonal graphene via Raman spectroscopy. Analysis of bare-, PMMA-covered supported, and PMMA-covered suspended graphene exhibits that their G and 2D band positions are progressively downshifted in that order. Mapping of spatial G and 2D band shifts into doping and strain contributions shows that PMMA residue exerts moderate 0.15% tensile strain on graphene/substrate, as compared to that of bare graphene. During this tensile strain, residual PMMA-covered graphene maintains its doping level as much as bare graphene does. (C) 2015 Elsevier Ltd. All rights reserved.