• 文献标题:   Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
  • 文献类型:   Article
  • 作  者:   MHAMANE D, SURYAWANSHI A, BANERJEE A, ARAVINDAN V, OGALE S, SRINIVASAN M
  • 作者关键词:   electrochemical electrode, graphene, secondary cell, supercapacitor
  • 出版物名称:   AIP ADVANCES
  • ISSN:   2158-3226
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   10
  • DOI:   10.1063/1.4802243
  • 出版年:   2013

▎ 摘  要

In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non-aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and power densities of 60.4 Wh kg(-1) and 0.15 kW kg(-1), respectively. More importantly, symmetric supercapacitor shows an extraordinary cycleability (5000 cycles) with over 80% of capacitance retention. In addition, Li-storage properties of TRGO are also evaluated in half-cell configuration (Li/TRGO) and shown to deliver a reversible capacity of similar to 705 mAh g(-1) with good cycleability at constant current density of 37 mA g(-1). This result clearly suggests that green-synthesized graphene can be effectively used as a prospective electrode material for non-aqueous energy storage systems such as Li-ion batteries and supercapacitors. Copyright 2013 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License. [http://dx.doi.org/10.1063/1.4802243]