• 文献标题:   Uniform-dispersed ZnS quantum dots loading on graphene as a promising anode for potassium-ion batteries
  • 文献类型:   Article
  • 作  者:   QI YQ, YANG Y, HOU Q, ZHANG K, ZHAO H, SU HJ, ZHOU LJ, LIU XR, SHEN C, XIE KY
  • 作者关键词:   zns quantum dot, morphologycontrollable, volume effect, anode, potassiumion batterie
  • 出版物名称:   CHINESE CHEMICAL LETTERS
  • ISSN:   1001-8417 EI 1878-5964
  • 通讯作者地址:  
  • 被引频次:   15
  • DOI:   10.1016/j.cclet.2020.08.030 EA APR 2021
  • 出版年:   2021

▎ 摘  要

The potassium-ion batteries (PIBs) have become the promising energy storage devices due to their relatively moderate cost and plenteous potassium resources. Whereas, the main drawback of PIBs is unsatisfactory electrochemical performance induced by the larger ionic radius of potassium ion. Herein, we report a well-designed, uniform-dispersed, and morphology-controllable zinc sulfide (ZnS) quantum dots loading on graphene as an anode in the PIBs. The directed uniform dispersion of the in-situ growing ZnS quantum dots (similar to 2.8 nm in size) on graphene can mitigate the volume effect during the insertionextraction process and shorten the migration path of potassium ions. As a result, the battery exhibits superior cycling stability (350.4 mAh/g over 200 cycles at 0.1 A/g) and rate performance (98.8 mAh/g at 2.0 A/g). We believe the design of active material with quantum dot-minimized size provides a novel route into PIBs and contributes to eliminating the major electrode failure issues of the system. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.