• 文献标题:   Effect of graphene doping of holographic polymer-dispersed liquid crystals
  • 文献类型:   Article
  • 作  者:   KIM BK, JANG MW, PARK HC, JEONG HM, KIM EY
  • 作者关键词:   conductivity, dispersion, graphene, hpdlc, morphology, polyurethane
  • 出版物名称:   JOURNAL OF POLYMER SCIENCE PART APOLYMER CHEMISTRY
  • ISSN:   0887-624X
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   24
  • DOI:   10.1002/pola.25909
  • 出版年:   2012

▎ 摘  要

Doping a polymer matrix with a minute amount of graphene (0.050.25%) had significant effects on the grating formation kinetics and electro-optical performance of a holographic polymer-dispersed liquid crystal. Low graphene contents (=0.1%) reduced the viscosity and induced rapid diffusion, curing, grating formation, and high diffraction efficiency with a diffraction overshoot of 0.05%. Conversely, high graphene contents increased the compound viscosity, and the entire process proceeded slowly. Graphene increased the polymer conductivity and local electric field, reduced the operating voltage from 65 to 2550 V, and increased the contrast ratio from 7 to 823 with a concomitant decrease in rise time. (c) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012