• 文献标题:   Modification of palladium-copper thin film by reduced graphene oxide or platinum as catalyst for Suzuki-Miyaura reactions
  • 文献类型:   Article
  • 作  者:   HOSEINI SJ, AGAHI BH, FARD ZS, FATH RH, BAHRAMI M
  • 作者关键词:   catalyst, oilwater interface, organometallic complex, platinum, palladium, copper nanoparticle, suzukimiyaura crosscoupling reaction
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Univ Yasuj
  • 被引频次:   16
  • DOI:   10.1002/aoc.3607
  • 出版年:   2017

▎ 摘  要

This study describes the synthesis of PdCu, PdCu/reduced graphene oxide and PtPdCu nanoparticle thin films via a simple reduction of organometallic precursors including [PtCl2(cod)] and [PdCl2(cod)] (cod = cis,cis-1,5-cyclooctadiene) complexes, in the presence of [Cu(acac)(2)] (acac = acetylacetonate) complex at toluene-water interface. The structure and morphology of the thin films were characterized using energy-dispersive analysis of X-rays, X-ray diffraction and transmission electron microscopy techniques. Our studies show that all of these nanoparticles are suitable for the Suzuki-Miyaura coupling (SMC) reaction in water. PtPdCu and PdCu thin films showed higher catalytic activity compared to Pd thin film in the SMC reaction due to the appropriate interaction among palladium, platinum and copper metals.