• 文献标题:   Facile microwave-assisted synthesized reduced graphene oxide/tin oxide nanocomposite and using as anode material of microbial fuel cell to improve power generation
  • 文献类型:   Article
  • 作  者:   MEHDINIA A, ZIAEI E, JABBARI A
  • 作者关键词:   electrode modification, tin oxide nanoparticle, graphene oxide, microbial fuel cell, power generation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Iranian Natl Inst Oceanog Atmospher Sci
  • 被引频次:   52
  • DOI:   10.1016/j.ijhydene.2014.05.008
  • 出版年:   2014

▎ 摘  要

A new nanocomposite material was fabricated by a facile and reliable method for microbial fuel cell (MFC) anode. Tin oxide (SnO2) nanoparticles were anchored on the surface of reduced graphene oxide (RGO/SnO2) in two steps. The hydrothermal method was used for the modification of GO and then microwave-assisted method was used for coating of SnO2 on the modified GO. Nanohybrids of RGO/SnO2 achieved a maximum power density of 1624 mW M-2, when used as the MFC anode. The obtained power density was 2.8 and 4.8 times larger than that of RGO coated and bare anodes, respectively. The electrodes were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The electrochemical characteristics were also studied by cyclic voltammetry (CV), linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The high conductivity and large specific surface of the nanocomposite were greatly improved the bacterial biofilm formation and increased the electron transfer. The results demonstrate that the RGO/SnO2 nanocomposite was advantageous material for the modification of anode and enhanced electricity generation of MFC. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.