• 文献标题:   Graphene Aerogels with Anchored Sub-Micrometer Mulberry-Like ZnO Particles for High-Rate and Long-Cycle Anode Materials in Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   FAN LS, ZHANG Y, ZHANG Q, WU X, CHENG JH, ZHANG NQ, FENG YJ, SUN KN
  • 作者关键词:   energy material, graphene aerogel, hierarchical structure, lithium ion batterie, electrode material
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   42
  • DOI:   10.1002/smll.201601817
  • 出版年:   2016

▎ 摘  要

Graphene aerogels (GAs) anchoring hierarchical, mulberry-like ZnO particles are fabricated in situ using a one-step solvothermal reaction. The resulting composites can function as anodes in lithium ion batteries, where they exhibit a high capacity and cyclic stability. The reversible capacities obtained are 365, 320, and 230 mA h g(-1) at current densities of 1, 2, and 10 A g(-1). Their high reversible capacity is 445 mA h g(-1) at a current density of 1.6 A g(-1); this value is maintained even after the 500th cycle, The excellent electrochemical performance is attributed to strong oxygen bridges between ZnO and graphene, where C-O-Zn linkages provide a good pathway for electron transport during charge/discharge cycles. Additionally, the hierarchical structure of the ZnO microballs suppresses stacking among the graphene layers, allowing the GAs to accelerate the transport of lithium ions. Furthermore, the GA framework enhances the electrical conductivity and buffer any volume expansion.