• 文献标题:   Preparation of Highly Dispersed Gold Nanoparticles on Organosilane Modified Graphene Nanosheets
  • 文献类型:   Article
  • 作  者:   LINGAPPAN N, KIM JH, GAL YS, LIM KT
  • 作者关键词:   silylation, go/au hybrid, graphene oxide, selfassembly, covalent functionalization, gold nanoparticle
  • 出版物名称:   MOLECULAR CRYSTALS LIQUID CRYSTALS
  • ISSN:   1542-1406 EI 1563-5287
  • 通讯作者地址:   Pukyong Natl Univ
  • 被引频次:   2
  • DOI:   10.1080/15421406.2014.944750
  • 出版年:   2014

▎ 摘  要

In this study, we present a novel strategy for the immobilization of gold nanoparticles (AuNPs) on the surfaces of modified graphene oxide (MGO/Au) using (3-mercaptopropyl) trimethoxysilane as a bridging agent. In the fabrication process, the hydroxyl functionalized GO was covalently functionalized with (3-mercaptopropyl) trimethoxysilane through C-O-Si linkage and the terminal thiol groups were further used to fabricate MGO/Au hybrids via the specific interaction between -SH and Au. The degree of covalent functionalization and fabrication of MGO/Au hybrid materials were confirmed with Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, thermal gravimetric analysis and high resolution transmission electron microscopy (HRTEM) analyses. HRTEM images demonstrated that the AuNPs were homogeneously distributed on the surfaces of GO. The MGO/Au hybrid showed enhanced thermal stability due to the intrinsic properties of graphene and gold nanoparticles.