• 文献标题:   In Situ Reduction of Graphene Oxide in an Epoxy Resin Thermally Cured with Amine
  • 文献类型:   Article
  • 作  者:   SANGERMANO M, TAGLIAFERRO A, FOIX D, CASTELLINO M, CELASCO E
  • 作者关键词:   conductivity, epoxy polymer, graphene oxide, xps
  • 出版物名称:   MACROMOLECULAR MATERIALS ENGINEERING
  • ISSN:   1438-7492 EI 1439-2054
  • 通讯作者地址:   Politecn Torino
  • 被引频次:   12
  • DOI:   10.1002/mame.201300286
  • 出版年:   2014

▎ 摘  要

A procedure is proposed to prepare electrically conductive epoxy resin composites exploiting in situ reduction of graphene oxide (GOx) during the epoxy thermal curing in presence of amine. The optimum curing conditions are evaluated, and the efficiency of the reduction process of GOx induced by amine is confirmed by XPS analyses. The composites electrical resistivity show a decrease by increasing filler amount, and this can only be due to the partial restoration of the conductive sp(2) structure occurred during thermal curing. This is a simple, easy-to-scale, one-step process to obtain electrically conductive epoxy cured materials by mixing the resin components and the well dispersible insulating GOx.