• 文献标题:   Vertical Graphene Arrays as Electrodes for Ultra-High Energy Density AC Line-Filtering Capacitors
  • 文献类型:   Article
  • 作  者:   XU SC, WEN YY, CHEN Z, JI NN, ZOU ZG, WU MM, QU LT, ZHANG J
  • 作者关键词:   electric field, filtering capacitor, phase angle, specific areal capacitance, strictly vertical graphene array
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1002/anie.202111468 EA OCT 2021
  • 出版年:   2021

▎ 摘  要

High-frequency responsive electrochemical capacitor (EC), as an ideal lightweight filtering capacitor, can directly convert alternating current (AC) to direct current (DC). However, current electrodes are stuck in limited electrode area and tortuous ion transport. Herein, strictly vertical graphene arrays (SVGAs) prepared by electric-field-assisted plasma enhanced chemical vapour deposition have been successfully designed as the main electrode to ensure ions rapidly adsorb/desorb in richly available graphene surface. SVGAs exhibit an outstanding specific areal capacitance of 1.72 mF cm(-2) at phi(120)=80.6 degrees even after 500 000 cycles, which is far better than that of most carbon-related materials. Impressively, the output voltage could also be improved to 2.5 V when using organic electrolyte. An ultra-high energy density of 0.33 mu Wh cm(-2) can also be handily achieved. Moreover, ECs-SVGAs can well smooth arbitrary AC waveforms into DC signals, exhibiting excellent filtering performance.