• 文献标题:   Enhanced non-enzymatic glucose sensing based on copper nanoparticles decorated nitrogen-doped graphene
  • 文献类型:   Article
  • 作  者:   JIANG D, LIU Q, WANG K, QIAN J, DONG XY, YANG ZT, DU XJ, QIU BJ
  • 作者关键词:   nitrogendoped graphene, cu nanoparticle, biosensor, glucose
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   144
  • DOI:   10.1016/j.bios.2013.11.005
  • 出版年:   2014

▎ 摘  要

Copper nanoparticles (NPs) decorated nitrogen-doped graphene (Cu-N-G) was prepared by a facile thermal treatment, and further employed as a novel sensing material for fabricating the sensitive nonenzymatic glucose sensor. Compared with pure Cu NPs, the Cu-N-G showed enhanced electrocatalytic activity to glucose oxidation due to the integration of N-G, which exhibited the oxidation peak current of glucose ca. 23-fold higher than that of pure Cu NPs. The presented sensor showed excellent performances for glucose detection including wide linear range of 0.004-4.5 mM, low detection limit (1.3 mu M, S/N=3), high sensitivity (48.13 mu A mM(-1)), fast response time (< 5 s), good selectivity to the general coexisted interferences, etc. Such properties would promote the potential application of the nitrogen-doped graphene as enhanced materials in fabricating sensors for chemical and biochemical analysis. (C) 2013 Elsevier B.V. All rights reserved.