• 文献标题:   Sulfur/Nitrogen Dual-doped Porous Graphene Aerogels Enhancing Anode Performance of Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   SHAN H, LI XF, CUI YH, XIONG DB, YAN B, LI DJ, LUSHINGTON A, SUN XL
  • 作者关键词:   hydrothermal selfassembly, dualdoped, graphene aerogel, lithium ion batterie, anode material
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tianjin Normal Univ
  • 被引频次:   65
  • DOI:   10.1016/j.electacta.2016.04.105
  • 出版年:   2016

▎ 摘  要

Sulfur/nitrogen dual-doped graphene aerogels (SNGAs) with a unique porous network structure have been designed through a facile and versatile one-pot hydrothermal strategy. When employed as anode in LIBs, the SNGAs with nitrogen content of 1.50 wt.% and sulfur content of 15.11 wt.% exhibit superior cycle life and rate capability. For example, a high reversible capacity of 1109.8 mAh g(-1) can be obtained after 400 cycles even at a high current density of 800 mA g(-1). It was discreetly demonstrated that the prominent improved performance of SNGAs can be mainly ascribed to the effect of dual-doping heteroatoms in cooperation with each other in to the graphene lattice as well as the porous nanostructure facilitating the mass transfer for both ions and electrons. Our conclusions illustrate that the strategy of dual-doped graphene aerogel may promote the potential application of graphene for high performance lithium ion batteries. (C) 2016 Elsevier Ltd. All rights reserved.