• 文献标题:   Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation
  • 文献类型:   Article
  • 作  者:   WIETECHA MS, ZHU J, GAO GH, WANG N, FENG H, GORRING ML, KASNER ML, HOU SF
  • 作者关键词:   platinum nanoparticle, graphene oxide, fuel cell, electrochemical catalyst, methanol
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Montclair State Univ
  • 被引频次:   48
  • DOI:   10.1016/j.jpowsour.2011.09.073
  • 出版年:   2012

▎ 摘  要

Platinum nanoparticles (Pt-NPs) were deposited onto N-(trimethoxy-silylpropyl) ethylenediamine triacetic acid (EDTA-silane) modified reduced graphene oxide (EDTA-RGO). The EDTA-RGO/Pt-NPs were coated onto a glass carbon electrode and characterized using scanning electron microscopy, transmission electron microscopy. X-ray diffraction, Raman spectra, and electrochemical tests. The chelating groups create a micro-environment that is suitable for the catalytic behavior of Pt-NPs. Compared with traditional carbon-based Pt catalysts, EDTA-RGO/Pt-NPs exhibit great tolerance towards poisoning by CO. Graphene-supported Pt nanoparticles can be used for the fabrication of fuel cell electrodes and other catalytic devices. (C) 2011 Elsevier B.V. All rights reserved.