• 文献标题:   Functionalized Graphene as a Gatekeeper for Chiral Molecules: An Alternative Concept for Chiral Separation
  • 文献类型:   Article
  • 作  者:   HAUSER AW, MARDIROSSIAN N, PANETIER JA, HEADGORDON M, BELL AT, SCHWERDTFEGER P
  • 作者关键词:   chiral separation, enantiomer, graphene, racemic mixture
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Calif Berkeley
  • 被引频次:   23
  • DOI:   10.1002/anie.201403145
  • 出版年:   2014

▎ 摘  要

We propose a new method of chiral separation using functionalized nanoporous graphene as an example. Computational simulations based on density functional theory show that the attachment of a suitable chiral bouncer molecule to the pore rim prevents the passage of the undesired enantiomer while letting its mirror image through.