• 文献标题:   Growths of mechanical elasticity and electrical conductance of graphene nanoplatelet/poly(lactic acid) composites under strong electric field: correlation with time evolution of higher order structure of graphene nanoplatelets
  • 文献类型:   Article
  • 作  者:   KWON OM, WATANABE H, AHN KH, LEE SJ
  • 作者关键词:   electric field, graphene nanoplatelet, polymer rheology, dielectric measurement, polymer nanocomposite
  • 出版物名称:   RHEOLOGICA ACTA
  • ISSN:   0035-4511 EI 1435-1528
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   0
  • DOI:   10.1007/s00397-017-1042-z
  • 出版年:   2017

▎ 摘  要

For a composite of poly(lactic acid) containing graphene nanoplatelets (GNPs) at a low concentration (0.34 vol%), this study examined growths of mechanical and electrical properties under an alternating current (AC) electric field, focusing on field-induced GNP structures governing those properties. The composite was subjected to the AC field (60 Hz) of various intensities E for various times t (E) at 190 A degrees C. A fraction of randomly oriented GNPs was aligned by the field and then connected into columns, as suggested from optical microscopy. This structural evolution led to qualitatively similar growths of low-frequency storage modulus and static electrical conductivity. The key quantity for understanding this growth was a time t (E)* for occurrence of short circuit that detected formation of GNP columns conductively bridging the electrodes. The growths of both modulus and conductivity for various E were summarized as functions of a reduced variable, t (E)/t (E)*, confirming the growths commonly reflected the evolution of the GNP columns. However, the modulus grew fast and leveled off by t (E)/t (E)* similar to 1, whereas the conductivity kept growing gradually even at t (E)/t (E)* > 1. This difference was discussed in relation to the matrix chains and leftover GNPs out the column.